Definitely. Podman Desktop lacks the onerous commercial license restrictions that Docker Desktop has, which is what drove me to set this up. Getting the Docker Desktop licenses tracked and paid at work was more hassle than setting up Docker manually. But Podman Desktop doesn't have any of that hassle, which is awesome.
Note that you don't need Podman Desktop if you don't want the UI. That is the sweet spot that we landed on. Of course if you want the UI that is fine as well - they just aren't bundled together in the same way. Of course, as you pointed out, even Docker / Docker Desktop isn't quite as coupled as it appears on the surface which is great to know.