I went through a search for quality headphones that can also work for Skype calls a while back. I ended up going with what is marketed as a gaming headset. While I'm not a gamer, I've found the SteelSeries Siberia V2 to be pretty great.
Happy to see someone else mention steelseries. The headphones I love are the 5H V2 though. They sound great to me, but more important for long sessions is that they are fantastically comfortable. Not only do they fit completely over my ears but the foam is marvelously soft and supple, unlike anything I've seen on other headphones.
Personally I use a pair of Shure SE-215-K in-ear monitors with the "Shure CBL-M+-K" cable that includes in-cord mic and volume adjustment. That cord will work with any in-ear monitor in the Shure SE line. I highly recommend this route if you're looking to spend within in the $150 to $500 range.
The pull-out mic is by far my favorite feature.
http://steelseries.com/products/audio/steelseries-siberia-v2