That page specifically says their work is funded. I’m sure all the core members do a ton of volunteer work for Debian, but I believe they are now being paid for work on reproducible builds.
It's funded by donation to Reproducible Builds project, and donation is managed by Software Freedom Conservancy (free software organization which also manages donation for Git, QEMU, Samba, and Wine). It's not like they are paid by their employers.
You can donate yourself. It is tax-deductible in US.