That's also a highly effective mitigation against legitimate users, especially those already disadvantaged everywhere else by a lack of disposable income.
Charging goes well for many online services. Hosted email, hosted VPS, and hosted SaaS are some that come to mind. Apple Store and Google Play charge to host mobile games.
Now they need to subpoena both PyPI and the payment processor. It does slow them down but effectively does nothing to "thwart future subpoenas from the total surveillance state".
One point of view is that in the general case this problem is solvable, has been solved, and the solution isn't well known.